Dice peppers and zucchini. Place in Round Steamer. Add seasoning; stir to evenly coat.
Stir in water, broth mix, and rice. Microwave, uncovered, on high for 16–18 min, until rice is tender.
Meanwhile, in a bowl, toss frozen shrimp and peas with smoked paprika; stir into cooked rice mix. Cover, then microwave on high, 2 min or until shrimp are warmed through.
Spoon into bowls and top with a dollop of aioli and add fresh cilantro, if desired.